Hafnium and neodymium isotopes in surface waters of the eastern Atlantic Ocean: Implications for sources and inputs of trace metals to the ocean   总被引：1，自引：0，他引：1  

J. Rickli  M. Frank  S. Aciego  R.B. Georg 《Geochimica et cosmochimica acta》2010,74(2):540-452

We present hafnium (Hf) and neodymium (Nd) isotopic compositions and concentrations in surface waters of the eastern Atlantic Ocean between the coast of Spain and South-Africa. These data are complemented by Hf and Nd isotopic and concentration data, as well as rare earth element (REE) concentrations, in Saharan dust.Hafnium concentrations range between a maximum of 0.52 pmol/kg in the area of the Canary Islands and a minimum value of 0.08 pmol/kg in the southern Angola Basin. Neodymium concentrations also show a local maximum in the area of the Canary Islands (26 pmol/kg) but are even higher between ∼20°N and ∼4°N reaching maximum concentrations of 35 pmol/kg. These elevated concentrations provide evidence of inputs from weathering of the Canary Islands and from the partial dissolution of dust from the Sahara/Sahel region. The inputs from ocean island weathering are also reflected in radiogenic Hf and Nd isotopes.The Hf isotopic compositions of dust samples themselves are highly variable, ranging between ε_Hf = −20 and −0.6. The combined Hf and Nd isotopic compositions of dust plot close to the “terrestrial array” during periods of appreciable dust load in the atmosphere. During low atmospheric dust loading combined Hf and Nd isotopic compositions similar to seawater are observed. Most of the variability can be explained in terms of variable degrees of zircon loss from the dust samples, which in turn is linked to sorting during atmospheric transport to the eastern Atlantic Ocean and possibly presorting by sedimentary redistribution on the continent. In addition, increasing relative proportions of radiogenic clay minerals with decreasing grain size may contribute to the radiogenic Hf isotopic compositions observed.While the Nd isotopic composition in the surface ocean reflects the Nd isotopic composition of the Saharan dust adjacent to the Sahara/Sahel region, the release of Hf from that dust appears to be incongruent and results in surface ocean Hf isotopic compositions which are ∼10 ε_Hf more radiogenic than the bulk dust. Radiogenic Hf appears to be released from clays and possibly from trace apatite. Rare earth element patterns of dust samples indicate the presence of apatite but provide no evidence for ferromanganese grain coatings, suggesting that such coatings are insignificant in the release of Hf and Nd from Saharan dust to the surface ocean.The Nd isotopic composition of the surface waters becomes less radiogenic south of the equator, most likely reflecting the release of Nd from Congo river sediments. The release of Hf from Saharan dust and the Congo river sediments, however, does not produce distinct Hf isotopic signatures in the surface ocean, implying that the mobile fraction of Hf integrated over large continental areas is isotopically uniform. The Hf isotopic uniformity in the surface ocean means that the limited variability in deep water isotopic compositions is consistent with a short deep water residence time and reflects homogenous continental inputs rather than efficient deep water homogenization.  相似文献   

Sequestration of a Biologically Labile Organic Carbon in Soils by Humified Organic Matter     

Allessandro Piccolo  Riccardo Spaccini  Rolf Nieder  Joerg Richter 《Climatic change》2004,67(2-3):329-343

In a long-term (one year) experiment, a sandy Podzol and a silty-loamy Loess soil were treated with labile (polysaccharides, AG) and stable (mature compost, CMP, and two humic acids from compost, HAC, and lignite, HAL) organic matter and the organic carbon (OC) lost by mineralization was periodically evaluated. The stable materials alone induced a significant reduction of OC losses in Podzol CMP <, HAL, <, HAC, Control), whereas the same treatments, except for CMP, produced an OC loss larger than control in Loess. This was attributed to the diverse textural and physical status of the two soils. The added stable organic matter became protected in the Podzol soil within the aggregates formed by the interaction with the coarse inorganic phase, while it was more easily decomposed in the Loess soils due to the strength of the native humic-clay complexes. In both soils, when the stable organic materials were mixed with polysaccharides (AG), the OC losses from this labile fraction were significantly reduced, being CMP more OC sequestering than HAC and HAL, in the order. These results confirmed that labile organic matter in soils can be protected from biodegradation by repartition into the hydrophobic domains of the stable, humified organic matter. This study suggests that mature compost and humic acids may usefully integrate management practices aimed to sequester organic carbon in soils.  相似文献   

Diffusion of Ar in muscovite     

T. Mark Harrison  Julien Célérier  Joerg Hermann 《Geochimica et cosmochimica acta》2009,73(4):1039-1051

Hydrothermal treatment of closely sized muscovite aggregates in a piston-cylinder apparatus induced ⁴⁰Ar^∗ loss that is revealed in ⁴⁰Ar/³⁹Ar step heating spectra. Age spectra and Arrhenius data, however, differ from that expected from a single diffusion length scale. A numerical model of episodic loss assuming the presence of multiple diffusion domains yields excellent fits between synthetic and actual degassing spectra. We used this model to isolate ⁴⁰Ar^∗ loss from the grains that remained intact during hydrothermal treatment at 10 kbar permitting calculation of diffusion coefficients in the temperature range 730-600 °C. Diffusion data generated in this manner yield an activation energy (E) of 63 ± 7 kcal/mol and frequency factor (D_o) of 2.3  cm²/s. Experiments at 20 kbar yield diffusivities lower by about an order of magnitude and correspond to an activation volume of ∼14 cm³/mol. Together, these parameters predict substantially greater retentivity of Ar in muscovite than previously assumed and correspond to a closure temperature (T_c) of 425 °C for a 100 μm radius grain cooling at 10 °C/Ma at 10 kbar (T_c = 405 °C at 5 kbar. Age and log (r/r_o) spectra for the run products show strong correlations indicating that muscovites can retain Ar diffusion boundaries and mechanisms that define their natural retentivity during vacuum step heating. This may permit the application of high resolution, continuous ⁴⁰Ar/³⁹Ar thermochronology to low grade, regionally metamorphosed terranes.  相似文献   

A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores     

Sarah M. Aciego  Bernard Bourdon  Maarten Lupker  Joerg Rickli 《Chemical Geology》2009,266(3-4):203-213

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.  相似文献   

Glacial and environmental changes over the last 60 000 years in the Polar Ural Mountains,Arctic Russia,inferred from a high‐resolution lake record and other observations from adjacent areas     

John Inge Svendsen  Lars Martin B. Frseth  Richard Gyllencreutz  Haflidi Haflidason  Mona Henriksen  Morten N. Hovland   ystein S. Lohne  Jan Mangerud  Dmitry Nazarov  Carl Regnll  Joerg M. Schaefer 《Boreas: An International Journal of Quaternary Research》2019,48(2):407-431

Our knowledge about the glaciation history in the Russian Arctic has to a large extent been based on geomorphological mapping supplemented by studies of short stratigraphical sequences found in exposed sections. Here we present new geochronological data from the Polar Ural Mountains along with a high‐resolution sediment record from Bolshoye Shchuchye, the largest and deepest lake in the mountain range. Seismic profiles show that the lake contains a 160‐m‐thick sequence of unconsolidated lacustrine sediments. A well‐dated 24‐m‐long core from the southern end of the lake spans the last 24 cal. ka. From downward extrapolation of sedimentation rates we estimate that sedimentation started about 50–60 ka ago, most likely just after a large glacier had eroded older sediments from the basin. Terrestrial cosmogenic nuclide (TCN) exposure dating (¹⁰Be) of boulders and Optically Stimulated Luminescence (OSL) dating of sediments indicate that this part of the Ural Mountains was last covered by a coherent ice‐field complex during Marine Isotope Stage (MIS) 4. A regrowth of the glaciers took place during a late stage of MIS 3, but the central valleys remained ice free until the present. The presence of small‐ and medium‐sized glaciers during MIS 2 is reflected by a sequence of glacial varves and a high sedimentation rate in the lake basin and likewise from ¹⁰Be dating of glacial boulders. The maximum extent of the mountain glaciers during MIS 2 was attained prior to 24 cal. ka BP. Some small present‐day glaciers, which are now disappearing completely due to climate warming, were only slightly larger during the Last Glacial Maximum (LGM) as compared to AD 1953. A marked decrease in sedimentation rate around 18–17 cal. ka BP indicates that the glaciers then became smaller and probably disappeared altogether around 15–14 cal. ka BP.  相似文献   

Monuments under threat: environmental impact, preservation strategies and natural stone recourses     

Siegfried Siegesmund  Joerg Ruedrich 《Environmental Earth Sciences》2011,63(7-8):1413-1414

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Large wood potential,piece characteristics,and flood effects in Swiss mountain streams     

Christian Rickli  Alexandre Badoux  Dieter Rickenmann  Nicolas Steeb  Peter Waldner 《自然地理学》2018,39(6):542-564

We present results of two studies on the (1) potential wood load in steep headwater streams and (2) properties of large wood (LW) transported in mountain rivers during the large August 2005 flood event in Switzerland. Ten headwater reaches of 1000 m length were surveyed in different regions of Switzerland. The potential wood load was estimated for in-channel deadwood, and possible driving factors were explored. Correlations were found with dead wood volume on hillslopes and mean channel width. We established size distributions of LW pieces and identified probable recruitment processes. Four reaches were resurveyed after an exceptionally severe flood in August 2005, showing limited LW transport in channels but considerable wood input by mass wasting processes. In addition, characteristics of deposits of LW along mountain rivers affected by the 2005 flood were investigated. Diameter and length distribution of transported and deposited pieces were comparable to those of LW from steep headwater streams, yet with considerably fewer long pieces in the deposits of mountain rivers. Most LW pieces were fresh wood, indicating that the portion of in-channel deadwood transported during the 2005 flood was limited. Findings of the study contribute to a better understanding of LW dynamics in Alpine mountain streams.  相似文献   

Preliminary 10Be chronology for the last deglaciation of the western margin of the Greenland Ice Sheet     

Vincent Rinterknecht  Yuri Gorokhovich  Joerg Schaefer  Marc Caffee 《第四纪科学杂志》2009,24(3):270-278

The now acknowledged thinning of the Greenland Ice Sheet raises concerns about its potential contribution to future sea level rise. In order to appreciate the full extent of its contribution to sea level rise, reconstruction of the ice sheet's most recent last deglaciation could provide key information on the timing and the height of the ice sheet at a time of rapid climate readjustment. We measured ¹⁰Be concentrations in 12 samples collected along longitudinal and altitudinal transects from Sisimiut to within 10 km of the Isunguata Sermia Glacier ice margin on the western coast of Greenland. Along the longitudinal transect, we collected three perched boulders and two bedrocks. In addition, we sampled seven perched boulders along a vertical transect in a valley within 10 km of the Isunguata Sermia Glacier ice margin. Our pilot dataset constrains the height of the ice sheet during the Last Glacial Maximum (LGM) between 500 m and 840 m (including the 120 m relative sea level depression at the time of the LGM, 21 ka BP). From the transect we estimate the thinning of the ice sheet at the end of the deglaciation between 12.3 ± 1.5 ¹⁰Be ka (n = 2) and 8.3 ± 1.2 ¹⁰Be ka (n = 3) to be ～6 cm a^?1 over this time period. Direct dating of the retreat of the western margin of the Greenland Ice Sheet has the potential to better constrain the retreat rate of the ice margin, the thickness of the former ice sheet as well as its response to climate change. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Clumped-isotope geochemistry of carbonates: A new tool for the reconstruction of temperature and oxygen isotope composition of seawater     

Stefano M. Bernasconi  Thomas W. Schmid  Anna-Lena Grauel  Joerg Mutterlose 《Applied Geochemistry》2011

Clumped-isotope geochemistry deals with the state of ordering of rare isotopes in molecules, in particular with their tendency to form bonds with other rare isotopes rather than with the most abundant ones. Among its possible applications, carbonate clumped-isotope thermometry is the one that has gained most attention because of the wide potential of applications in many disciplines of the earth sciences. In particular, it allows reconstructing the temperature of formation of carbonate minerals without knowledge of the isotopic composition of the water from which they were formed. In addition, the O isotope composition of the waters from which they were formed can be calculated using the δ¹⁸O of the same carbonate sample. This feature offers new approaches in paleoclimatology for reconstructing past global geochemical cycles. In this contribution two applications of this method are presented. First the potential of a new analytical method of measurement of clumped isotopes on small samples of foraminifera, for high-resolution SST and seawater δ¹⁸O reconstructions from marine sediments is shown. Furthermore the potential of clumped isotope analysis of belemnites, for reconstructing seawater δ¹⁸O and temperatures in the Cretaceous is shown.  相似文献   

Erratum: Late glacial and holocene 10Be production rates for western Norway     

Brent M. Goehring  Øystein Strand Lohne  Jan Mangerud  John Inge Svendsen  Richard Gyllencreutz  Joerg Schaefer  Robert Finkel 《第四纪科学杂志》2012,27(5):544-544

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